Diagnostics and monitoring of cultural heritage
sites are mandatory as part of the preservation of
artistic artifacts. The more delicate and prone to
degradation a work of art is, the more efficient and
informative a diagnostic technique must be. The
innovative techniques described in this paper were
applied to the study of walls, whether painted or
unpainted, to determine the moisture content and
degree of salinity to gather information about the
porosity in the sub-surface, and to detect the
presence of voids and anomalies at a depth of
several tens of millimeters. The techniques used
(evanescent field dielectrometry [EFD], unilateral
nuclear magnetic resonance [NMR] and holographic
radar) were largely complementary. EFD
and unilateral NMR can measure the water present
in a wall from a few to approximately 20 mm
beneath the surface. EFD can detect the presence
of soluble salts before efflorescence takes place;
unilateral NMR can estimate the porosity of a wall;
and holographic radar can provide information
about the texture of a wall and detect any large
detachments and cavities present therein. The
above techniques were applied to the ancient
San Rocco Church located in Cornaredo, a small
town near Milan, Italy. These techniques were
applied on a very degraded fresco painting, with
the main objective of quantifying the increasing
dampness. As a result, moisture and salinity
images of the wall were obtained by EFD and
unilateral NMR, determining the moisture distribution
from a depth of 5 to 20 mm inside the wall,
and the distribution of soluble salts in the subsuperficial
layer. Furthermore, the presence of
detachments and material anomalies were
detected by means of a holographic radar survey.
Arnold, J., C. Clauser, R. Pechnig, S. Anferova, V. Anferov and B. Blümich,
“Porosity and Permeability from Mobile NMR Core-scanning,” Petrophysics,
Vol. 47, No. 4, 2006, pp. 306–314.
Blümich, B., J. Perlo and F. Casanova, “Mobile Single-sided NMR,”
Progress in Nuclear Magnetic Resonance Spectroscopy, Vol. 52, No. 4, 2008,
pp. 197–269.
Capineri, L., P. Falorni, G. Borgioli, T. Bechtel, S. Ivashov, A. Zhuravlev, I.
Vasiliev, M. Paradiso and G. Cartocci, “Application of the Holographic
Radar RASCAN to Cultural Heritage Inspection,” Advances in Remote
Sensing for Archaeology and Cultural Heritage Management, 30 September –
4 October 2008, pp. 1–13.
Capineri, L., P. Falorni, S. Ivashov, A. Zhuravlev, I. Vasiliev, T. Bechtel and
G. Stankiewicz, “Combined Holographic Subsurface Radar and Infrared
Thermography for Diagnosis of the Conditions of Historical Structures
and Artworks,” Near Surface Geophysics, Vol. 8, No. 5, October 2010,
pp. 355–364.
Capitani, D., N. Proietti, M. Gobbino, L. Soroldoni, U. Casellato, M.
Valentini and E. Rosina, “An Integrated Study for Mapping the Moisture
Distribution in an Ancient Damaged Wall Painting,” Analytical and Bioanalytical
Chemistry, Vol. 395, 2009, pp. 2245–2253.
CNR-ICR, Assorbimento d’Acqua per Capillarità – Coefficiente di Assorbimento
Capillare (Water Absorption by Capillarity Capillarity Absorption
Coefficient), Italian Recommendation Normal – 11/85, 1985.
Di Tullio, V., N. Proietti, M. Gobbino, D. Capitani, R. Olmi, S. Priori, C.
Riminesi and E. Giani, “Non-destructive Mapping of Dampness and Salts
in Degraded Wall Paintings in Hypogeous Buildings: The Case of St.
Clement at Mass Fresco in St. Clement Basilica, Rome,” Analytical and
Bioanalytical Chemistry, Vol. 396, 2010, pp. 1885–1896.
Dunn, K. J., D. J. Bergman and G. A. Latorraca, Nuclear Magnetic Resonance
Petrophysical and Logging Applications (Handbook of Geophysical Exploration:
Seismic Exploration), Pergamon, Oxford, UK, 2002.
Eidmann, G., R. Savelsberg, P. Blümler and B. Blümich, “The NMR
MOUSE, a Mobile Universal Surface Explorer,” Journal of Magnetic Resonance
A, Vol. 122, 1996, pp. 104–109.
Grote, K., S. Hubbard and Y. Rubin, “Field-scale Estimation of Volumetric
Water Content Using GPR Groundwave Techniques,” Water Resources
Research, Vol. 39, No. 11, 2003, p. 1321.
Laurens, S., J. Rhazi, J.Balayssac and J. Bisaro, “Influence of Concrete
Surface Moisture on the Direct Radar Wave,” Bulletin Des Laboratoires Des
Ponts Et Chaussées, Vol. 239, 2002.
Mitchell, J., P. Blümler and P. J. McDonald, “Spatially Resolved Nuclear
Magnetic Resonance Studies of Planar Samples,” Progress in Nuclear
Magnetic Resonance Spectroscopy. Vol. 48, 2006, pp. 161–181.
Olmi, R. and C. Riminesi, “Study of Water Mass Transfer Dynamics in
Frescoes by Dielectric Spectroscopy”, Il Nuovo Cimento, Vol. 31, No. 3,
2008, pp. 389–402.
Olmi, R., M. Bini, A. Ignesti, S. Priori, C. Riminesi and A. Felici, “Diagnostics
and Monitoring of Frescoes Using Evanescent-field Dielectrometry,”
Measurement Science and Technology, Vol. 17, No. 8, 2006, pp. 2281–2288.
Perlo, J., F. Casanova and B. Blümich, Journal of Magnetic Resonance,
Vol. 176, 2005, pp. 64–70.
Proietti, N., D. Capitani, R. Lamanna, F. Presciutti, E. Rossi and A. L.
Segre, “Fresco Paintings Studied by Unilateral NMR,” Journal of Magnetic
Resonance, Vol. 177, No. 1, 2005, pp. 111–117.
Proietti, N., D. Capitani, S. Cozzolino, M. Valentini, E. Pedemonte, E.
Princi, S. Vicini and A.L. Segre, “In Situ and Frontal Polymerization for the
Consolidation of Porous Stones: A Unilateral NMR and Magnetic Resonance
Imaging Study,” Journal of Physical Chemistry B, Vol. 110, November
2006, pp. 23719–23728.
Proietti, N., D. Capitani, E. Rossi, S. Cozzolino and A. L. Segre, “Unilateral
NMR Study of a XVI Century Wall Painted,” Journal of Magnetic Resonance,
Vol. 186, No. 2, 2007, pp. 311–318.
RiMiDiA, Riflettometria a Microonde per la Diagnostica di beni Artistici
(Microwave Reflectometry for the Diagnostics of Artistic heritage),
http://rimidia.det.unifi.it, POR-CreO FESR 2007-2013 Asse 1 Attività 1.1
Linea di intervento D, Tuscany Region, 2010.
Sharma, S., F. Casanova, W. Wache, A. L. Segre and B. Blümich, “Analysis
of Historical Porous Building Materials by the NMR-MOUSE,” Magnetic
Resonance Imaging, Vol. 21, Nos. 3–4, 2003, pp. 249–255.
Vandevoorde, D., M. Pamplona, O. Schalm, Y. Vanhellemont, V. Cnudde
and E. Verhaeven, “Contact Sponge Method: Performance of a Promising
Tool for Measuring the Initial Water Absorption,” Journal of Cultural
Heritage, Vol. 10, No. 1, 2009, pp. 41–47.
Watson, A. T. and C. T. P. Chang, “Characterizing Porous Media with
NMR Methods,” Progress in Nuclear Magnetic Resonance,, Vol. 32, 1998,
pp. 343–386.
Windsor, C. G., A. Bulletti, L. Capineri, P. Falorni, G. Borgioli, M. Inagaki,
T. D. Bechtel, E. Bechtel, A. V. Zhuravlev, and S. Ivashov, “A Single Display
for RASCAN 5-frequency 2-polarisation Holographic Radar Scans,”
PIERS, Vol. 5, No. 5, 2009, pp. 496–500.